Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex
نویسندگان
چکیده
منابع مشابه
A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials.
The synthesis and characterisation of a new, highly luminescent inorganic cluster complex, (Bu4N)2[Mo6I8(NO3)6], are described. The complex possesses labile nitrato ligands and is therefore a useful precursor for the design of new luminescent materials. To exemplify this, functionalised polystyrene beads have been utilised as "polymeric ligands" to immobilise the molybdenum cluster complex.
متن کاملOctahedral molybdenum cluster complexes with aromatic sulfonate ligands.
This article describes the synthesis, structures and systematic study of the spectroscopic and redox properties of a series of octahedral molybdenum metal cluster complexes with aromatic sulfonate ligands (nBu4N)2[{Mo6X8}(OTs)6] and (nBu4N)2[{Mo6X8}(PhSO3)6] (where X- is Cl-, Br- or I-; OTs- is p-toluenesulfonate and PhSO3- is benzenesulfonate). All the complexes demonstrated photoluminescence ...
متن کاملA supramolecular approach to fabricate highly emissive smart materials
The aromatic chromophores, for example, perylene diimides (PDIs) are well known for their desirable absorption and emission properties. However, their stacking nature hinders the exploitation of these properties and further applications. To fabricate emissive aggregates or solid-state materials, it has been common practice to decrease the degree of stacking of PDIs by incorporating substituents...
متن کاملSimulation of crystal and electronic structures of octahedral molybdenum cluster complex compound Cs2[Mo6Cl14] using various DFT functionals
*Department of Metallurgy and Ceramics Science, Tokyo Institute of Technology, 2–12–1 Ookayama, Meguro, Tokyo 152–8551, Japan **National Institute for Materials Science, 1–1 Namiki, Tsukuba, Ibaraki 305–0044, Japan ***NIMS-Saint-Gobain Center of Excellence for Advanced Materials, National Institute for Materials Science, 1–1 Namiki, Tsukuba, Ibaraki 305–0044, Japan ****Institut des Sciences Chi...
متن کاملCharacterization of Catalytically Active Octahedral Metal Halide Cluster Complexes
Halide clusters have not been used as catalysts. Hexanuclear molecular halide clusters of niobium, tantalum, molybdenum, and tungsten possessing an octahedral metal framework are chosen as catalyst precursors. The prepared clusters have no metal–metal multiple bonds or coordinatively unsaturated sites and therefore required activation. In a hydrogen or helium stream, the clusters are treated at...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of Materials Chemistry C
سال: 2016
ISSN: 2050-7526,2050-7534
DOI: 10.1039/c5tc03204k